Changes in phase structure and features of distribution and migration of atoms in metals and alloys at treatment by the electrical discharges in a liquid at low temperatures are investigated. The velocities of diffusion and form of concentration profiles are determined depending on temperature, multiplicity of loads, method of pulse effect, structure of an alloy and kind of penetrating atoms. The tendencies to both the atomic mobility decrease with growth of the number of pulse loads and the mobility increase with increase of pulse energy are revealed. The phase structure of a diffusion zone is determined at penetration of nickel, aluminium, carbon and oxygen atoms into iron.

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