Within the frames of the model of the polyassociative solutions the comparative analysis was performed of the formation parameters of multi-atom complexes in CdTe and Hg - Te systems. It was shown, that thermodynamical properties of the studied systems can be described in the supposition of the presence in the liquid phase of the ATe, A2Te3, ATe2, A2Te (A = Cd, Hg) and free Te, Cd, Hg atoms. In accordance with the model of polyassociative solutions the data on p - T - x equilibrium in the region of quasi-binary cross-section of Cd - Hg - Te system structural diagram were obtained. It was shown, that the mixing effects in the three-component liquid phase are satisfactorily described by the formation of CdHgTe and CdHgTe3 associates. The good correspondence of the calculations and experiment in the high temperature part of the Cd - Hg - Te system structural diagram was achieved.

Індекс рубрикатора НБУВ: В379.25в641.0

Шифр НБУВ: Ж16425 Пошук видання у каталогах НБУВ 

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