Implantation of Cu6PS5X (X = I, Br) single crystals was carried out for different values of fluence with using P<^>+ ions; the energy of ions was 150 keV. For the implanted Cu6PS5X crystals, the structural studies were performed using the scanning electron microscopy technique and energy-dispersive X-ray spectroscopy. Spectrometric studies of optical absorption edge and luminescence were carried out within the temperature range 77 - 320 K. The influence of ionic implantation on luminescence spectra, parameters of Urbach absorption edge, parameters of exciton-phonon interaction as well as ordering-disordering processes in Cu6PS5X (X = I, Br) superionic conductors have been studied.

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