The kinetics of separate crystallization of phases in slowly cooled alloys of various structures of the peritectical system Ag - Cd is investigated. The models of mass growth of crystals are developed. If the primary crystal's share exceeds some critical value (<$E eta~>>~eta sub roman cr>), it is impossible to neglect the diffusion in the solid phase. If <$E eta~<<~eta sub roman cr>, then mass transfer in the liquid phase can be carried out not only by diffusion, but also by natural convection. The formulas for the relative amount of primary crystals formed under crystallization according to the specified models are given.

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